Lateral electron transport in monolayers of short chains at interfaces: A Monte Carlo study

0301-0104/$ see front matter 2010 Elsevier B.V. A doi:10.1016/j.chemphys.2010.04.041 * Corresponding author. E-mail address: [email protected] (C.B Using Monte Carlo simulations, we study lateral electronic diffusion in dense monolayers composed of a mixture of redox-active and redox-passive chains tethered to a surface. Two charge transport mechanisms are considered: the physical diffusion of electroactive chains and electron hopping between redox-active sites. Results indicate that by varying the monolayer density, the mole fraction of electroactive chains, and the electron hopping range, the dominant charge transport mechanism can be changed. For high density monolayers in a semi-crystalline phase, electron diffusion proceeds via electron hopping almost exclusively, leading to static percolation behavior. In fluid monolayers, the diffusion of chains may contribute more to the overall electronic diffusion, reducing the observed static percolation effects. 2010 Elsevier B.V. All rights reserved.